SAFETY DATA SHEETS
According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition
Version: 1.0
Revision Date: Aug 12, 2017
SECTION 1 IDENTIFICATION
1.1GHS Product identifier
|
Product name
|
calcium dichloride
|
1.2Other means of identification
|
Product number
|
-
|
|
Other names
|
DBO4
|
1.3Recommended use of the chemical and restrictions on use
|
Identified uses
|
For industry use only. Food additives
|
|
Uses advised against
|
no data available
|
1.4Supplier's details Hualong Nitrite Limited. Dongfeng Street East High-tech Zone,Weifang Shandong,China
1.5Emergency phone number
|
Emergency phone number
|
0086-536-8899207
|
|
Service hours
|
Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).
|
SECTION 2 HAZARDS IDENTIFICATION
2.1Classification of the substance or mixture
Eye irritation, Category 2
2.2GHS label elements, including precautionary statements
|
Pictogram(s)
|
|
|
Signal word
|
Warning
|
|
Hazard statement(s)
|
H319 Causes serious eye irritation
|
|
Precautionary statement(s)
|
|
|
Prevention
|
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
|
|
Response
|
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
|
|
Storage
|
none
|
|
Disposal
|
none
|
2.3Other hazards which do not result in classification
none
SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS
3.1Substances
|
Chemical name
|
Common names and synonyms
|
CAS number
|
EC number
|
Concentration
|
|
calcium dichloride
|
calcium dichloride
|
10043-52-4
|
none
|
100%
|
SECTION 4 FIRST AID MEASURES
4.1Description of necessary first-aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
Fresh air, rest. Refer for medical attention.
In case of skin contact
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer immediately for medical attention.
In case of eye contact
Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.
If swallowed
Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer immediately for medical attention.
4.2Most important symptoms/effects, acute and delayed
Inhalation causes irritation of nose and throat. Ingestion causes irritation of mouth and stomach. Contact with eyes (particularly by dust) causes irritation and possible transient corneal injury. Contact of solid with dry skin causes mild irritation; strong solutions can cause marked irritation, even a superficial burn. (USCG, 1999)
4.3Indication of immediate medical attention and special treatment needed, if necessary
Absorption, Distribution and Excretion
Approximately 80% of body calcium is excreted in the feces as insoluble salts; urinary excretion accounts for the remaining 20%.
SECTION 5 FIREFIGHTING MEASURES
5.1Extinguishing media
Suitable extinguishing media
In case of fire in the surroundings, use appropriate extinguishing media.
5.2Specific hazards arising from the chemical
no data available
5.3Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6 ACCIDENTAL RELEASE MEASURES
6.1Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
6.2Environmental precautions
Personal protection: complete protective clothing including self-contained breathing apparatus. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.
6.3Methods and materials for containment and cleaning up
Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.
SECTION 7 HANDLING AND STORAGE
7.1Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
7.2Conditions for safe storage, including any incompatibilities
Separated from zinc. Dry. Well closed.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1Control parameters
Occupational Exposure limit values
no data available
Biological limit values
no data available
8.2Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
8.3Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Respiratory protection
Wear dust mask when handling large quantities.
Thermal hazards
no data available
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
|
Physical state
|
white solid
|
|
Colour
|
no data available
|
|
Odour
|
no data available
|
|
Melting point/ freezing point
|
782oC
|
|
Boiling point or initial boiling point and boiling range
|
1935°C/1atm(lit.)
|
|
Flammability
|
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
|
|
Lower and upper explosion limit / flammability limit
|
no data available
|
|
Flash point
|
>1600oC
|
|
Auto-ignition temperature
|
no data available
|
|
Decomposition temperature
|
no data available
|
|
pH
|
no data available
|
|
Kinematic viscosity
|
no data available
|
|
Solubility
|
In water:740 g/L (20 oC)
|
|
Partition coefficient n-octanol/water (log value)
|
no data available
|
|
Vapour pressure
|
0.01 mm Hg ( 20 °C)
|
|
Density and/or relative density
|
1.086g/mLat 20°C
|
|
Relative vapour density
|
no data available
|
|
Particle characteristics
|
no data available
|
SECTION 10 STABILITY AND REACTIVITY
10.1Reactivity
no data available
10.2Chemical stability
Stable under recommended storage conditions.
10.3Possibility of hazardous reactions
Bromine trifluoride rapidly attacks calcium chloride [Mellor 2 Supp. 1:164, 165 1956]. Long term exposure of calcium chloride solution upon a zinc coated galvanized iron vessel caused slow evolution of hydrogen which ignited and exploded [Bretherick, 5th Ed., 1995].
10.4Conditions to avoid
no data available
10.5Incompatible materials
no data available
10.6Hazardous decomposition products
no data available
SECTION 11 TOXICOLOGICAL INFORMATION
Acute toxicity
· Oral: no data available
· Inhalation: no data available
· Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
SECTION 12 ECOLOGICAL INFORMATION
12.1Toxicity
· Toxicity to fish: no data available
· Toxicity to daphnia and other aquatic invertebrates: no data available
· Toxicity to algae: no data available
· Toxicity to microorganisms: no data available
12.2Persistence and degradability
no data available
12.3Bioaccumulative potential
no data available
12.4Mobility in soil
no data available
12.5Other adverse effects
no data available
SECTION 13 DISPOSAL CONSIDERATIONS
13.1Disposal methods
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14 TRANSPORT INFORMATION
14.1UN Number
|
ADR/RID: Not dangerous goods.
|
IMDG: Not dangerous goods.
|
IATA: Not dangerous goods.
|
14.2UN Proper Shipping Name
|
ADR/RID: unknown
|
|
IMDG: unknown
|
|
IATA: unknown
|
14.3Transport hazard class(es)
|
ADR/RID: Not dangerous goods.
|
IMDG: Not dangerous goods.
|
IATA: Not dangerous goods.
|
14.4Packing group, if applicable
|
ADR/RID: Not dangerous goods.
|
IMDG: Not dangerous goods.
|
IATA: Not dangerous goods.
|
14.5Environmental hazards
|
ADR/RID: no
|
IMDG: no
|
IATA: no
|
14.6Special precautions for user
no data available
14.7Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
no data available
SECTION 15 REGULATORY INFORMATION
15.1Safety, health and environmental regulations specific for the product in question
|
Chemical name
|
Common names and synonyms
|
CAS number
|
EC number
|
|
calcium dichloride
|
calcium dichloride
|
10043-52-4
|
none
|
|
European Inventory of Existing Commercial Chemical Substances (EINECS)
|
Listed.
|
|
EC Inventory
|
Listed.
|
|
United States Toxic Substances Control Act (TSCA) Inventory
|
Listed.
|
|
China Catalog of Hazardous chemicals 2015
|
Not Listed.
|
|
New Zealand Inventory of Chemicals (NZIoC)
|
Listed.
|
|
Philippines Inventory of Chemicals and Chemical Substances (PICCS)
|
Listed.
|
|
Vietnam National Chemical Inventory
|
Listed.
|
|
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)
|
Listed.
|
SECTION 16 OTHER INFORMATION
Information on revision
|
|
|
|
Revision Date
|
Aug 12, 2017
|
Abbreviations and acronyms
· CAS: Chemical Abstracts Service
· ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
· RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
· IMDG: International Maritime Dangerous Goods
· IATA: International Air Transportation Association
· TWA: Time Weighted Average
· STEL: Short term exposure limit
· LC50: Lethal Concentration 50%
· LD50: Lethal Dose 50%
· EC50: Effective Concentration 50%
References
· IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
· HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
· IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
· eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
· CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
· ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
· ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
· Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
· ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
|
